MICAINKTM
Pigments for Inks
Copper Phthalo Cyanine Green 7
Version: No.01
Material Safety Data Sheet
MICAS ORGANICS LIMITED
www.micas.co.in
THE ESSENCE OF COLOURTM
MICAINKTM
Copper Phthalo Cyanine Green 7
Version: No.01
MICAS ORGANICS LIMITED
Plot No. 297/4-10, II Phase, GIDC
Vapi-396195. Gujarat (India).
Page : /8
2. HAZARDS IDENTIFICATION
Classification of substance or mixture
Not classified according to CLP-regulation.
Additional information on classification
Label elements Composition onthe label
Pigment Green 7:100 %
Other hazards Other hazards
Not known.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Substance
PIGMENT COPPER PHTHALOCYANINE GREEN 7
Composition
100% PIGMENT COPPER PHTHALOCYANINE GREEN 7
CAS No. Description
1328-53-6
EC No.
236-878-9
EINECS Number
74260
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product details
Trade Name
COPPER PHTHALOCYANINE GREEN 7
Synonyms
POLYCHLORO PHTHALOCYANINE
Use of the substance / the preparation
Colorants for Paints, Rubber, Printing inks, etc.
Company/undertaking identification
Supplier(Manufacturer)
Micas Organics Limited
Address
Plot No. 297 / 4 – 10 Phase II, GIDC, Vapi – 396195, Gujarat, India
Telephone
+91 260 3090000
Fax
+91 260 3090099
Emergency telephone No
+91 260 3090000
E-mail
info@micas.co.in
MICAINKTM
Copper Phthalo Cyanine Green 7
Version: No.01
MICAS ORGANICS LIMITED
Plot No. 297/4-10, II Phase, GIDC
Vapi-396195. Gujarat (India).
Page : /8
4. FIRST AID MEASURES
General information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Immediately remove any clothing soiled by the product.
After inhalation
Take affected persons into fresh air and keep quiet. In case of unconsciousness, place patient stably in side position for transportation. Call a doctor immediately.
After skin contact
Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor.
After eye contact
Rinse opened eye for several minutes under running water.Remove the contact lenses and open eyes wide apart. Seek immediate medical advice.
After swallowing
Drink plenty of water and provide fresh air. Call for a doctor immediately. Do not give victim anything to drink if he is unconscious. Treat symptomatically.
Specifically details on antidotes
No recommendation given.
5. FIRE FIGHTING MEASURES
Suitable extinguishing agents
Use fire extinguishing methods suitable to surrounding conditions.CO 2 , Dry chemical powder or water spray. Fightlarger fires with water spray or alcohol resistant foam.
For safety reasons unsuitable extinguishing agents
No information
Protective equipment
Wear self-contained respiratory protective device.
Additional information
Collect contaminated fire fighting water separately. It must not enter the sewage system. Hazardous combustion may create fumes/ gases of Hydrogen chloride (HCL), Carbon monoxide (CO), Carbon Dioxide (CO 2 )
6. ACCIDENTAL RELEASE MEASURES
Person-related safety precautions
Wear protective equipment. Keep unprotected persons away. Use respiratory protective device against the effects of fumes / dust / aerosol. Ensure adequate ventilation. Avoid formation of its dust.
MICAINKTM
Copper Phthalo Cyanine Green 7
Version: No.01
MICAS ORGANICS LIMITED
Plot No. 297/4-10, II Phase, GIDC
Vapi-396195. Gujarat (India).
Page : /8
Measures for environmental protection
Do not allow to enter sewers/ surface or ground water. Informrespective authorities in case of seepage into water course or sewage system. Do not allow to penetrate the ground/soil. In case of seepage into the ground inform responsible authorities.
Measures for cleaning/collecting
Dam and absorb spillages with sand, earth or other non-combustible material.
Additional information
No additional information.
7. HANDLING AND STORAGE
Handling
Mechanical ventilation may be required. Observe goodindustrial hygiene practices.
Information for safe handling
Wear suitable respiratory protective device when decanting larger quantities without extractor facilities. Ensure good ventilation / exhaustion at the workplace. Prevent formation of dust. Keep receptacles tightly sealed.
Information about fire - and explosion protection
Keep respiratory protective device available.
Storage
Keep away from heat, sparks and open flame. Store in a cool andwell ventilated place.
8. EXPOSURE CONTROLS / PPE
Additional information about design of technical facilities
No further data.
Ingredients with limit values thatrequire monitoring at the workplace
Not required
Additional information
The lists valid during the making were used as basis.
Personal protective equipment
-
General protective and hygienicmeasures
The usual precautionary measures are to be adhered to when handling chemicals. Do not eat, drink, smoke or sniff while working. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Shower or take a bath at the end of work. Store the protective clothing separately.
MICAINKTM
Copper Phthalo Cyanine Green 7
Version: No.01
MICAS ORGANICS LIMITED
Plot No. 297/4-10, II Phase, GIDC
Vapi-396195. Gujarat (India).
Page : /8
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure, use self- contained respiratory protective device.
Protection of hands
The glove material has to be impermeable and resistant to the product / the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
Body protection
Protective work clothing.
9. PHYSICAL / CHEMICAL PROPERTIES
General Information
Form
Fine Powder
Colour
Green
Odour
Odourless
PH
7.5+1
Flash point
Not applicable
Flammability (solid, gaseous)
Product is not flammable.
Danger of explosion
Product does not present an explosion hazard.
Specific gravity at 20°C
2.3 g/cm3
Solubility in / Miscibility with Water
Insoluble.
pH-value at 20°C
6–9
Organic solvents
0,0 %
Solids content
100,0 %
MICAINKTM
Copper Phthalo Cyanine Green 7
Version: No.01
MICAS ORGANICS LIMITED
Plot No. 297/4-10, II Phase, GIDC
Vapi-396195. Gujarat (India).
Page : /8
10. STABILITY AND REACTIVITY
Thermal decomposition /Thermal decomposition/conditions to be avoided
No decomposition if used according to specifications.
Materials to be avoided
-
Dangerous reactions
No dangerous reactions known.
Dangerous decomposition products
No dangerous decomposition products known.
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Ld50 values relevant for classification
PIGMENT BLUE 15:3 Oral LD50 >5000 mg/kg (rat)
Primary irritant effect
On the skin
No irritant effect.
On the eye
No irritant effect.
Sensitization
No sensitizing effects known.
CMR effects (carcinogenetic, mutagenicity and toxicity for reproduction)
None
12. ECOLOGICAL CONSIDERATIONS
Information about elimination(persistence and degradability)
This product is expected to be not readily biodegradable.
Ecological effects
Aquatic acute Fish LC 50- 250mg/l (Yzias latipes species 48hr)
Additional ecological information
Not Known
13. DISPOSAL CONSIDERATIONS
Product
Recommendation
Must be specially treated adhering to official regulations. It Must not be disposed together with household garbage. Do not allow product to reach sewage system.
MICAINKTM
Copper Phthalo Cyanine Green 7
Version: No.01
MICAS ORGANICS LIMITED
Plot No. 297/4-10, II Phase, GIDC
Vapi-396195. Gujarat (India).
Page : /8
14. TRANSPORT INFORMATION
Land Transport ADR/RID [cross-border]
Not dangerous goods in the meaning of ADR/RID, ADNR,IMDG-Code, ICAO/IATA-DGR
ADR/RID Class
-
Danger Code
-
UN-Number
-
Packaging group
-
Hazard label
-
Special marking
-
Description of goods
-
Tunnel restriction code
-
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
-
15. REGULATORY INFORMATION
Safety Health and environmental regulations/legislation specificfor the substance or mixture
Other Label Information Regulation
(EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments.
Legislation and regulations
Dangerous Substance Directive 67/548/EEC. The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). The List of Wastes (England) (Amendment) Reg ulations 2005. (SI 2005 No. 895). Avfallsförordningen (2011:927).
Unclean packaging Recommendation
Its Packaging that may not be cleansed are to be disposed of in the same manner as the product.
MICAINKTM
Copper Phthalo Cyanine Green 7
Version: No.01
MICAS ORGANICS LIMITED
Plot No. 297/4-10, II Phase, GIDC
Vapi-396195. Gujarat (India).
Page : /8
16. OTHER INFORMATION
These data are based on our present knowledge & are intended to describe the product with regard to the safety requirements. The data shall not constitute a guarantee of a particular or general specification nor shall it establish a legally valid contractual relationship. It will be a sole responsibility of the user of the product to ensure the suitability of the product intended for the purpose & method of use.
Department issuing MSDS
Technical & Customer support
Contact
Jignesh Oza
info@micas.co.in
ABBREVIATIONS AND ACRONYMS
ADR : Accord européen sur le transport des merchandises dangerous par Route (European Agreementconcerning the International
Carriage of Dangerous Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer(Regulations Concerning the International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA : International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
Lc50: Lethal concentration, 50 percent
Ld50: Lethal dose, 50 percent